Indeed, in this type of feedhorn, I think the LNB that is directly aligned with the feedhorn has its polarity set by the shape of the tube, as it transitions to rectangular. and if you look inside you see a little metal thing encased in plastic (that thing is really an antenna) that transports the other polarity signal to the second LNB opening.
As for the C/KU combo LNBFs, I had the opportunity to try one on an 8-foot dish, and all I could get was the strongest transponders, such as CGTN on 95W, and JBS on 99W. From what I understand it's basicaly a C-Band LNBF, and they made a hole at the end and mounted a Ku LNBF. But the built-in feedhorn is really tuned for C-Band and the Ku LNB gets limited signal. From what I read, it works fine on some dishes and really poorly on others.
Instead, on my 10-ft dish I attached a cheap Ku LNBF to the side of the C-Band scalar, and it's working quite well. Of course one drawback is that Ku- and C-Band are not aligned, so that's many more entries in the positionner. (I also added a circular polarization feedhorn on the opposite side of the scalar)